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新型熱電SnSe半導體晶體研究進展

Recent Progress of Novel Thermoelectric SnSe Semiconductor Crystal

  • 摘要: SnSe晶體是一種新型Ⅳ-Ⅵ族化合物半導體熱電材料,具有極低的本征熱導率和超高的熱電優值ZT,因兼具有高性能、環境友好以及成本低廉等綜合優勢,近些年正成為國際上爭相研究的熱點。然而SnSe晶體屬於層狀結構材料且熱膨脹性復雜,導致晶體在生長過程中極易出現解理和開裂,難以獲得大尺寸晶體。本文對當前國內外幾種主流SnSe晶體生長方法進行了歸納,包括水平氣相法、垂直布裏奇曼法、垂直溫度梯度法等,綜合評價了各種方法的優缺點。重點介紹了本團隊在水平布裏奇曼法生長SnSe晶體方面的研究結果,該方法有望成為未來製備高質量、大尺寸SnSe晶體的一種主流技術。此外,還將不同SnSe晶體的熱電優值ZT進行了比較,並對其性能波動進行了初步分析。本綜述論文將有助於加深人們對SnSe晶體生長特性的認識,並為未來該晶體材料製備和性能研究提供參考。

     

    Abstract: SnSe crystal is novel Ⅳ-Ⅵ group compound semiconductor thermoelectric material, it has very low intrinsic thermal conductivity and ultra-high figure of merit ZT value. Due to its high performance, environmental friendly and low cost advantages, the research of SnSe crystal has become a hot point around the world. However, the growth of large size SnSe crystal is hard mainly because of its layer crystal structure and complicated thermal expansion behavior. In this paper, some growth methods for SnSe crystal growth are introduced and compared, such as horizontal vapour method, vertical Bridgman method and vertical gradient frozen method. Additionally, the growth result of SnSe by a horizontal Bridgman method in our group is also reported which is concluded would be a key technology for high quality and large size SnSe crystal growth in the future. Moreover, the figure of merit ZT of different SnSe crystals is also compared, and its value variation is analyzed. This review paper would be helpful for deep understanding the growth character of SnSe crystal, and it will provide suggestions for SnSe crystal fabrication and property investigation in future.

     

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