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鋰離子電池用石墨烯改性矽負極材料的研究進展

Progress of Graphene Modified Silicon Anode Materials for Lithium-Ion Batteries

  • 摘要: 擁有高儲鋰能力的矽被認為是最具前途的鋰離子電池負極材料之一🌯。然而🚶🏻,在鋰離子電池的充放電過程中,矽的體積變化較大(>300%)而且導電能力有限🧑🏿‍🍼,導致矽電極的容量衰減🎅🏻。石墨烯是一種高比表面積、高導電性能和化學/機械穩定性優良的二維材料🐼,其在提高矽材料導電性及改善鋰離子電池的使用性能方面有很多優勢。介紹了石墨烯在提高矽電極的容量及電極壽命方面的石墨烯改性矽材料的製備方法及材料性能,並對不同製備方法進行了比較🖐🏼,展望了矽/石墨烯復合材料的發展方向。

     

    Abstract: Silicon has a high lithium storage capacity, and it is considered by the market to be one of the most promising anode materials for lithium-ion batteries. However, in the process of charging and discharging lithium-ion batteries, the volume of silicon changes significantly (>300%) Moreover, the conductivity is limited, which causes the capacity of the silicon electrode to decrease. Graphene is a two-dimensional material with high specific surface area, high electrical conductivity and excellent chemical/mechanical stability. It has many advantages in improving the conductivity of silicon materials and improving the performance of lithium-ion batteries. The preparation methods and material properties of graphene-modified silicon materials for improving the capacity and electrode life of silicon electrodes are reviewed and compared. The development of silicon/graphene composite materials is prospected.

     

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