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鈣鈦礦核殼納米材料製備及應用進展

Progress in preparation and application of core-shell perovskite nanomaterials

  • 摘要: 鈣鈦礦納米材料具有優異的光物理特性和獨特的電子結構,因此具有發射光譜可調、高色純度、高吸收性、高載流子遷移率等特性,在光電器件、光伏和光催化領域有著巨大的前景。傳統II-VI族量子點同樣具有形狀、尺寸、帶隙和光學性質可調等優點。將傳統量子點(例如II-VI族和III-V族量子點)和鈣鈦礦材料結合形成的鈣鈦礦核殼納米材料在穩定性和光電性能方面均有顯著提升。綜述了此種新型鈣鈦礦核殼納米材料的不同合成方法,並討論了其光電性質以及界面處的載流子動力學問題,以期為鈣鈦礦核殼納米材料的合成和應用提供參考。

     

    Abstract: The excellent photophysical properties and unique electronic structure of perovskite nanomaterials, lead to adjustable photoluminescence spectrum, high color purity, high absorption, and high carrier mobility. Therefore, they have attracted huge attention in the fields of optoelectronic devices, photovoltaics, and photocatalysis. Typical quantum dots also have the advantages of adjustable shape, size, band gap, and optical properties. The combination of typical (such as group II-VI and III-V) quantum dots and perovskite nanomaterials to form a novel core-shell perovskite nanomaterials have significantly improved their stability and photoelectric performance. This paper reviews different preparation methods for this novel core-shell perovskite quantum dot nanomaterials, as their photoelectric properties, and carrier dynamics at the interface. This provides guidance for improving the properties of core-shell perovskite nanomaterials and optimizing their preparation methods and application.

     

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